PUBLICATIONS

Journals

  • 94

    A waterwheel hybrid generator with disk triboelectric nanogenerator and electromagnetic generator as a power source for an electrocoagulation system

    Abstract

    Electrocoagulation (EC) method has emerged as a state-of-the-art water purifying technology. Here, a self-powered EC system is proposed using a waterwheel hybrid generator (W-HG) based on disk-type triboelectric nanogenerator (D-TENG) and electromagnetic generator (EMG). D-TENG consists of a rotator and stator based on printed circuit board (PCB) technology. With electrospinning and sintering process for polytetrafluoroethylene (PTFE) as a dielectric layer of the D-TENG, the fabricated membrane exhibits superhydrophobic property with a water contact angle of 160.5°, which allows the device to show self-cleaning property and to operate at high relative humidity. Additionally, a fractal-design based switched-capacitor-converter (FSCC) is utilized with the high-frequency and high-output based D-TENG to operate commercial electronic devices. The hybridized W-HG exhibits 1.75 mW of the average power at the matching load resistance of 400 Ω. An energy conversion efficiency of the device between rotational input energy and electrical output energy marks at 8.75%. The D-TENG and EMG are combined with a rotating waterwheel to demonstrate their ability to power an EC purification system. A power management integrated circuit (PMIC) is utilized with the D-TENG for high current input to the EC module. Finally, the W-HG successfully purifies wastewater with a high removal ratio above 95% for 18 h.

    Graphical Abstract

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  • 93

    Rational design of cobalt-iron bimetal layered hydroxide on conductive fabric as a flexible battery-type electrode for enhancing the performance of hybrid supercapacitor

    Abstract

    Mixed metal hydroxide (MMH) based supercapacitor electrodes, with their outstanding performance from the synergistic effect originating from mixed metallic elements, can effectively address the drawbacks of single metal hydroxide (SMH) based electrodes. Owing to their superior electrochemical properties stemming from their unique structural and chemical compositional design, MMH electroactive materials have attracted considerable attention for energy storage devices. Among those devices, a layered double hydroxide (LDH) structure has been emerged as an alternative electrode due to its large interlayer arrangement, high redox activity, and multiple oxidation states. Herein, we have successfully designed cobalt-iron LDH nanosheets (CoFe LDH NSs) on nickel fabric by a facile electrochemical deposition (ECD) method with a chronoamperometry voltage of − 1.0 V for 100 s. Further, the unique as-fabricated structure that arises from the tunable chemical composition and wide variety of material properties was successfully manipulated to boost the electrochemical energy storage performance. Finally, the optimized electrode made of Co0.5Fe0.5 exhibited superior electrochemical performance due to its porous, surface-stimulated large electroactive area and high conductivity with great stability. By integrating a battery-type electrode of CoFe LDH and a capacitive-type electrode of activated carbon (AC), a hybrid supercapacitor (HSC) device was assembled. Besides, the high areal capacitance of 70 µF/cm2, it delivers high energy density (1.6 mWh/cm2) and power density (0.09 mW/cm2) values along with the excellent cycling stability (91% capacity retention). Moreover, the fabricated flexible device offers the significance as a power source in flexible electronic devices with its high degree of flexibility originated from flexible substrate. This work not only provides a promising electrode for supercapacitors, but also a unique structural and compositional design of electroactive materials for energy storage systems.

    Graphical Abstract

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  • 92

    Facile synthesis of MgCo2O4 hexagonal nanostructure via co-precipitation approach and its supercapacitive properties

    Summary

    Magnesium cobalt oxide (MgCo2O4) hexagonal nanoplates were prepared via a fast and simple co-precipitation process. The electrochemical properties of MgCo2O4 nanostructures were characterized by various techniques. Furthermore, the MgCo2O4 hexagonal nanoplate material was used for supercapacitors. In three-electrode scheme, MgCo2O4 hexagonal nanoplate electrode demonstrated a good specific capacity of 164 mAh g−1 at 3 A g−1. Furthermore, an aqueous asymmetric supercapacitor (ASC) using MgCo2O4//activated carbon (AC) was also fabricated. The MgCo2O4//AC delivered 39 mAh g−1 of specific capacity at 1 A g−1. It revealed the high energy density of 28.34 W h kg−1 with the power density of 363 W kg−1 with the current density of 0.5 A g−1. The impressive electrochemical performance is mainly associated to high surface area of 55 m2 g−1 resulted from voids/gaps in-between hexagonal nanoplates of MgCo2O4. Also, a toy motor fan, 11 light-emitting diodes (LEDs), and a kitchen timer were functionalized by series linked two ASCs for practical applications.

  • 91

    Effects of activated Sr2+ ion content on strong blue-emitting Ca2Sb2O7 materials for high-quality WLED devices

    Summary

    In this report, the luminescent performances of the self-host blue-emitting Ca2Sb2O7 materials were investigated in terms of the sintering temperature and the dopant Sr2+ ion content. The emission intensity was enhanced with an increase of the sintering temperature as well as the lattice parameters. After doping the Sr2+ ions (>1.2 mol%), the emission spectra of Ca2Sb2O7 materials would be redshifted. The blue-emitting color (Ca2Sb2O7) turned into greenish-blue (Sr2+@1.6 mol%) and green (Sr2+@2 mol%) colors in sequence. In light of these interesting findings, the crystal structure, elemental composition, morphology, thermal stability, luminescent dynamics, luminescent efficiency, etc were investigated and compared. Finally, the mini-white lighting-emitting diodes (WLEDs) based on the blue-emitting Ca2Sb2O7, greenish-blue-emitting Ca0.4Sr1.6Sb2O7, and green-emitting Sr2Sb2O7 phosphors were fabricated by mixing commercial phosphors (CP). Especially, the Ca2Sb2O7-CP-WLED and Sr2Sb2O7-CP-WLED devices exhibited a warm white light with good correlated color temperature (<3200 K) and excellent color-rendering index (>88). All the above results suggested that the self-host emitting materials of Sr2+ activated Ca2Sb2O7 with color-tunable properties could be very promising for solid-state lighting applications.

  • 90

    Antenna for IoT-Based Future Advanced (5G) Railway Communication With End-Fire Radiation

    Abstract:

    This work presents a design study of an antenna for future railway communications in the context of Internet of Things (IoT). 28-GHz resonance frequency has been considered for the 5G communication systems with end-fire radiations. The size of the proposed antenna array element is 100 mm ×20 mm. The shark-fin cover is used to cover the antenna to protect it from the external environmental effects. The proposed antenna along with the 1.3-GHz bandwidth centered at 28 GHz results an expected end-fire radiation ( θ=83 ), with a gain of >10 dBi and its suitability to be installed on the roof of the train for communications to the front and back directions along with the track has been studied and discussed in detail.
  • 89

    All-polymer waterproof triboelectric nanogenerator towards blue energy harvesting and self-powered human motion detection

    Abstract

    With growing energy crisis in this era, developing and utilizing sustainable energy sources are required because the conventional energy sources cannot be restored. Among the various sustainable energy sources, the ocean wave energy is considered as one of the best sustainable energy sources. However, the conventional technologies to harvest the ocean energy show some limitations such as corrosion. Hence, guaranteeing the high resistance to corrosion of the harvesting devices has become a critical challenge for ocean-energy harvesting. Herein, a mat-shaped solid-liquid triboelectric nanogenerator is fabricated to harvest the blue energy while overcoming the shortcomings of the conventional technologies. The fabricated device is composed of the polydimethylsiloxane embedded in a conductive carbon black utilized as the electrode of the proposed device and it can directly harvest the blue energy. Moreover, through acquired energy from the simulated waves, the fabricated device can operate an anemometer and can split the seawater to produce the hydrogen. Also, the human motions can be distinguished through the k-mean clustering method with the high classification of 96.67%. Considering these results, the fabricated device is expected to be utilized as the promising blue energy harvester as well as the self-powered human motion sensor in near future.

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  • 88

    Quantum dot-integrated GaN light-emitting diodes with resolution beyond the retinal limit

    Abstract and figures


    Near-eye display technology is a rapidly growing field owing to the recent emergence of augmented and mixed reality. Ultrafast response time, high resolution, high luminance, and a dynamic range for outdoor use are all important for non-pixelated, pupil-forming optics. The current mainstream technologies using liquid crystals and organic materials cannot satisfy all these conditions. Thus, finely patterned light-emissive solid-state devices with integrated circuits are often proposed to meet these requirements. In this study, we integrated several advanced technologies to design a prototype microscale light-emitting diode (LED) arrays using quantum dot (QD)-based color conversion. Wafer-scale epilayer transfer and the bond-before-pattern technique were used to directly integrate 5-µm-scale GaN LED arrays on a foreign silicon substrate. Notably, the lithography-level alignment with the bottom wafer opens up the possibility for ultrafast operation with circuit integration. Spectrally pure color conversion and solvent-free QD patterning were also achieved using an elastomeric topographical mask. Self-assembled monolayers were applied to selectively alter the surface wettability for a completely dry process. The final emissive-type LED array integrating QD, GaN, and silicon technology resulted in a 1270 PPI resolution that is far beyond the retinal limit.
    An overview of the key technologies used in this study to achieve an emissive-type RGB micro-LED array with over 1000-PPI resolution
a Wafer-scale GaN epilayer was transferred using a low temperature bonding process. b The epilayer was bonded with lithographic precision in alignment for future CMOS integration. c Surface energy was modified with self-assembled monolayers for dry patterning of QDs. d A double layer elastomeric mask was used to dry pattern the QDs without using any solvent. e QDs were used for spectrally pure color conversion.
    Fabrication of an epitaxial layer-transferred μ-LED and measurement results
a Schematic of wafer-scale epitaxial layer transfer and the μ-LED fabrication process. A cross-sectional SEM image of bonded eutectic metal alloys (without any voids) is shown on the top left. Schematic images and optical images of the substrate removal process is shown in top right. FE-SEM images of 5 μm-pixel μ-LED mesa structures and an optical image of LGD letter patterns with individual pixels shown are on the lower panel. b Collective current–voltage characteristics of 20,000-pixel μ-LEDs with varying metal mesh densities. c Light output power densities of μ-LED structures as a function of input power.
    Patterning of QD films using the elastomer-assisted dry-patterning process
a A schematic of the overall process of dry patterning of microscale QD pixels. b QD layer before the peel-off process. c Patterned individual QD pixels. d SEM image of a QD array with a single-color QD pattern. e SEM image of a QD array with both QDs sequentially patterned. f Illustration of the elastomeric mask used for QD dry patterning. g Isotropic SEM image of the patterned QD.
    Characterization of the QD-integrated full-color μ-LED display
a Photographic image of the wafer with an ultrafine pixel micro-LED array. b, c Microscopic images of the R/G single QD patterns under UV light with 10 and 5 μm pixels, respectively. All scale bars denote 20 μm. d A microscopic image of R/G double QD patterns under UV light. e A microscopic image of RGB pixels for the QD-integrated μ-LED arrays. f Schematic of the QD color conversion process. g PL spectra of the green/red QD layers. h Absorbance of the blue light from the LED as a function of QD film thickness. The absorbance is measured by subtracting the transmitted blue light power from the incident blue light power. i Normalized light power intensities of the absorbed blue light, emitted green light, and transmitted blue light as a function of the green QD film thickness. The EQE saturates as the QD thickness increases. j EQE and IQE as a function of the QD film thickness for both green and red QDs.
  • 87

    Influence of different flux-materials on phase structure, morphology, photoluminescence, thermal stability, and cathodoluminescence in Ba2La0.9Eu0.1SbO6 phosphors

    Abstract

    Recently, flux-materials have attracted considerable attention for improving the photoluminescence (PL) properties of luminescent materials. Herein, the phase structure, morphology, PL property, thermal stability, and cathodoluminescence (CL) property of Ba2La0.9Eu0.1SbO6 phosphors with and without the flux-materials of NH4F, C6H8O7, and H3BO3 were investigated and compared. At first, these mentioned flux-materials would barely affect the crystal structure through analyzing the X-ray diffraction patterns and Rietveld refinements. However, the morphology, PL intensity, thermal stability, lifetime, and CL performance were implicated by adding the flux-materials. Especially, the C6H8O7 flux-material could obviously improve the emission intensity and CL property of Ba2La0.9Eu0.1SbO6 phosphors with respect to the other samples. In addition, these flux-materials could enhance thermal stability and lifetime. In terms of quantum yield, the H3BO3 flux-material has the best optimization capabilities. Briefly, this work would provide a deep insight into a kind of suitable flux-materials to optimize luminescent materials in the synthesized processes.

    Graphical Abstract

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  • 86

    <p>Dopamine treated SnO2/PVDF composite films for hybrid mechanical energy harvester</p>

    Abstract

    Combining the piezoelectric and triboelectric effects into a single device called hybrid nanogenerator (HNG) is a key discovery to overcome the drawback of low electrical output piezo/triboelectric nanogenerators. This work elaborates detailed electrical performance investigation on dopamine treated tin oxide (DA@SnO2nanoparticles (NPs) impregnated polyvinylidene fluoride (PVDF)-based HNG. The mixing of SnO2 NPs inside the PVDF matrix enhances the β phase of the composite film and the electrical performance of the respective HNG. The coating of DA on SnO2 NPs works as a binder between SnO2 NPs and PVDF polymer by removing the defects in the SnO2/PVDF composite film. Also, the presence of carbon in DA increases electron generation inside the composite film, which further enhances the electrical output of HNG. With this effect, the fabricated DA@SnO2/PVDF-based HNG produced maximum electrical outputs of 62 V, 1.55 μA, and 17.9 μC/m2 which were considerably higher than those of the SnO2/PVDF-based HNG. Finally, the DA@SnO2/PVDF-based HNG was tested for different operational parameters and used to charge commercially available capacitors and power up small-scale electronics. The proposed HNG provides an excellent energy harvesting capability and can be employed to harvest energy from abundantly available mechanical movements.

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  • 85

    Prussian-Blue Analogue-Derived Hollow Structured Co3S4/CuS2/NiS2 Nanocubes as an Advanced Battery-Type Electrode Material for High-Performance Hybrid Supercapacitors

    Abstract

    The facile and cost-effective fabrication of hybrid nanostructures comprised of hollow mixed metallic chalcogenides has attracted growing interest in the development of high-performance energy storage devices. Herein, multi-component (nickel-cobalt-copper-sulfides/selenides (NCCS/NCCSe)) hollow nanocubes (HNCs) are prepared via a single-step sulfurization/selenization process. The NCCS material shows interior HNCs, and the NCCSe material exhibits slightly formed porous cubes. Both the prepared materials demonstrate higher charge storage performance than the precursor NCC NCs owing to the improved surface morphology and addition of sulfur and selenium ions. Particularly, the NCCS HNCs electrode reveals superior specific capacity (capacitance) (70.32 mAh g−1 (666.20 F g−1) at 5 mA cm−2) along with excellent cycling stability of 108.6% even after 10 000 cycles. Interestingly, the electrode delivers a good rate capability of 83.5% at a high current density of 20 mA cm−2. The feasibility of the battery-type NCCS HNCs as a positive electrode is explored by constructing an aqueous electrochemical hybrid capacitor (AEHC). The AEHC exhibits maximum energy and power densities of 23.15 Wh kg−1 and 7899.08 W kg−1, respectively. Remarkably, it demonstrates superior long-life cycling stability even after 10 000 cycles (120.6% retention). The suitability of AEHC for practical application is also tested by driving electronic devices.